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发布时间： 2015-12-29  浏览次数：

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  吴立明                
 

                    

教授，博士生导师。

毕业于澳门永利唯一官网304化学系（1993年理学学士，1996年理学硕士），师从刘若庄院士，主要开展有机分子电子结构计算研究；1999年毕业于福州大学化学系，获理学博士学位，研究方向为TiO2光催化反应的能带结构和理论。1999-2001年在中科院物构所做博士后，师从吴新涛院士，研究领域从理论化学拓展到了晶体合成及结构化学，确立了结构化学、理论化学与实验相结合的研究理念；2001-2004年在美国Arizona State University化学系从事博士后研究，师从Dong-Kyun Seo教授。2015年作为高级访问教授在美国Northewestern University澳门永利唯一官网304Mercouri G. Kanatzidis课题组从事研究工作。

2004年在中国科学院物质结构研究所任课题组组长，副研究员，博士生导师；2005-2014年在中国科学院物质结构研究所任课题组组长，研究员，博士生导师；2015年作为高层次人才引进到澳门永利唯一官网304，任教授、博士生导师。创建了澳门永利唯一官网304非线性光学材料和热电材料的研究领域，并取得了显著的研究成果。将结构化学、理论化学和实验结合，辅助新型功能材料的发现、判明功能材料性能提升的可行方向、以及阐明功能材料的结构-性能关系。近年来，针对氧族能量转换材料，我们通过理论计算和结构设计、结合实验合成和探测，提出了阳离子化学裁剪、协同取代等结构调控新策略及性能提升新方案；发现系列高效、有实用价值的窄带半导体热电材料和宽带非线性光学材料。非线性光学材料研究居于世界领先地位，其中我们引领的深紫外非线性光学研究领域连续两年入选物理类十大热门研究领域。培养研究生获得北京市优秀硕士毕业生、澳门永利唯一官网304优秀博士毕业生、国家奖学金、唐敖庆奖学金、中科院院长奖学金等。发表SCI期刊论文160余篇，获授权发明专利10余项。

             
 

通信地址：北京市海淀区学院南路12号，澳门永利唯一官网304化学院南院科技园小B座203室 邮编: 100875   

 

澳门永利唯一官网304珠海校区“先进材料研究中心”光电晶态材料研究所 广东省珠海市唐家湾金凤路18号 邮编: 519085           
 

电子邮箱：wlm@bnu.edu.cn

https://zkgyy.bnu.edu.cn/yjjg/xjclyjzx/xjclrcdw/107094.htm

 

学术兼职

2014-2018年 中国材料研究学会热电材料及应用分会 理事

2018-2022年 中国材料研究学会热电材料及应用分会 理事

2020年起应邀担任Journal of Solid State Chemistry 杂志国际编委

主要研究领域：

从事固体无机化合物合成、结构性能表征、成键分析和能带结构研究。重点研究领域为非线性光学材料和热电材料。

招生信息

每年招收博士生，硕士生；长期诚招博士后若干名。

博士后申请者具有量子化学、物理化学、物理专业的博士学位，具有非线性光学、热电材料等研究背景者优先考虑。

(https://zkgyy.bnu.edu.cn/yjjg/xjclyjzx/xjclrczp/107111.htm)

代表性论文

  1. Zhang, Z. P.; Liu, X.; Liu, X. M.; Lu, Z. W.; Sui, X.; Zhen, B. Y.; Lin, Z. S.; Chen, L.;* Wu, L. M.* Driving Nonlinear Optical Activity with Dipolar 2‑Aminopyrimidinium Cations in (C4H6N3)+(H2PO3)−. Chem. Mater. 2022, 34, 1976−1984.
  2. Liu, X.; Chen, L.;* Wu, L. M* Why does KBe2BO3F2 have Excellent Deep Ultraviolet Nonlinear Optical Properties? Sci. China. Chem. 2022, 48, 1–9.
  3. Ma, N.; Li, F.; Li, J. G.; Liu, X.; Zhang, D. B.; Li, Y. Y.; Chen, L.;* Wu, L. M.* Mixed-Valence CsCu4Se3: Large Phonon Anharmonicity Driven by the Hierarchy of the Rigid [(Cu+)4(Se2−)2](Se−) Double Anti-CaF2 Layer and the Soft Cs+ Sublattice. J. Am. Chem. Soc. 2021, 143, 18490−18501.
  4. Xiong, L.; Wu, L. M.;* Chen, L.* A General Principle for DUV NLO Materials: π-Conjugated  Confinement Enlarges Band Gap. Angew. Chem. Int. Ed. 2021, 60, 25063–25067.
  5. Yang, Y. C.; Liu, X.; Lu, J.; Wu, L. M.;* Chen, L.* [Ag(NH3)2]2SO4: A Strategy for the Coordination of Cationic Moieties to Design Nonlinear Optical Materials. Angew. Chem. Int. Ed. 2021, 60, 21216–21220.
  6. Lu, J.; Liu, X.; Zhao, M.; Deng, X. B.; Shi, K. X.; Wu, Q. R.; Chen, L.;* Wu, L. M.* Discovery of NLO Semiorganic (C5H6ON)+(H2PO4)−: Dipole Moment Modulation and Superior Synergy in Solar-Blind UV Region. J. Am. Chem. Soc. 2021, 143, 3647-3654.
  7. Jia, F.; Liu, Y. Y.; Zhang, Y. F.; Shu, X.; Chen, L.;* Wu, L. M.* Bi8Se7: Delocalized Interlayer π Bond Interactions Enhancing Carrier Mobility and Thermoelectric Performance Near Room Temperature. J. Am. Chem. Soc. 2020, 142, 12536−12543.
  8. Li, R. A.; Zhou, Z. Y.; Lian, Y. K.; Jia, F.; Jiang, X. X.; Tang, M. C.; Wu, L. M.;* Sun, J. L.;* Chen, L.* A2SnS5: Structural Incommensurate Modulation Exhibiting Strong Second-Harmonic Generation and High Laser Induced Damage Threshold (A = Ba, Sr). Angew. Chem. Int. Ed. 2020, 59 , 11861−11865.
  9. Pan, C. Y.; Yang, X. R.; Xiong, L.; Lu, Z. W.; Zhen, B. Y.; Sui, X.; Deng, X. B.; Wu, L. M.;* Chen, L.* Solid-State Nonlinear Optical Switch with the Widest Switching Temperature Range Owing to Its Continuously Tunable Tc. J. Am. Chem. Soc. 2020, 142 , 6423−6431.
  10. Ma, N.; Li, Y. Y.; Chen, L.;* Wu, L. M.* α‑CsCu5Se3: Discovery of a Low-Cost Bulk Selenide with High Thermoelectric Performance. J. Am. Chem. Soc. 2020, 142 , 5293−5303.
  11. Ma, N.; Xiong, L.; Chen, L.;* Wu, L. M.* Vibration Uncoupling of Germanium with Different Valence States Lowers Thermal Conductivity of Cs2Ge3Ga6Se14. Sci. China Mater. 2019, 62 (12): 1788–1797.
  12. Lu, J.; Lian, Y. K.; Xiong, L.; Wu, Q. R.; Zhao, M.; Shi, K. X.; Chen, L.;* Wu, L. M.* How To Maximize Birefringence and Nonlinearity of π‑Conjugated Cyanurates. J. Am. Chem. Soc. 2019, 141 , 16151−16159.
  13. Zhou, H. M.; Xiong, L.; Chen, L.;* Wu, L. M.* Dislocations that Decrease Size Mismatch within the Lattice Leading to Ultrawide Band Gap, Large Second-Order Susceptibility, and High Nonlinear Optical Performance of AgGaS2. Angew. Chem. Int. Ed. 2019, 58 , 9979−9983.
  14. Lu, J.; Yue, J. N.; Xiong, L.; Zhang, W. K.; Chen, L.;* Wu, L. M.* Uniform Alignment of Non-π-Conjugated Species Enhances Deep Ultraviolet Optical Nonlinearity. J. Am. Chem. Soc. 2019, 141 , 8093−8097.
  15. Xiong, L.; Chen, J.; Lu, J.; Pan, C. Y.; Wu, L. M.* Monofluorophosphate: A New Source of Deep-Ultraviolent Nonlinear Optical Materials. Chem. Mater. 2018, 30 , 7823−7830.
  16. Chen, J.; Xiong, L.; Chen, L.;* Wu, L. M.* Ba2NaClP2O7: Unprecedented Phase Matchability Induced by Symmetry Breaking and Its Unique Fresnoite-type Structure. J. Am. Chem. Soc. 2018, 140, 14082−14086.
  17. Ju, S. L.; + Bai, W.; + Wu, L. M.; + Lin, H.; Xiao, C.*; Cui, T. S.; Li, Z.; Kong, S.; Liu, Y.; Liu, D. Y.; Zhang, G. B.; Sun, Z.*; Xie, Y.* Evidence for Itinerant Carriers in an Anisotropic Narrow-Gap Semiconductor by Angle-Resolved Photoemission Spectroscopy. Adv. Mater. 2018, 30 , 1704733.
  18. Yin, X.; Liu, J. Y.; Chen, L.; Wu, L. M.* High Thermoelectric Performance of In4Se3-Based Materials and the Influencing Factors. Acc. Chem. Res. 2018, 51 , 240−247.
  19. Li, Y. Y.; Liu, P. F.; Wu, L. M.* Ba6Zn7Ga2S16: A Wide Band Gap Sulfide with Phase-Matchable Infrared NLO Properties. Chem. Mater . 2017, 29 , 5259−5266.
  20. Lin, H.; Chen, L.;* Yu, J. S.; Chen, H.; Wu, L. M.* Infrared SHG Materials CsM3Se6 (M = Ga/Sn, In/Sn): Phase Matchability Controlled by Dipole Moment of the Asymmetric Building Unit. Chem. Mater. 2017, 29 , 499–503.
  21. Lin, H.; Chen, H.; Zheng, Y. J.; Chen, Y. K.; Yu, J. S.; Wu, L. M.* Ba5Cu8In2S12: A Quaternary Semiconductor with a Unique 3D Copper-rich Framework and Ultralow Thermal Conductivity. Chem. Commun . 2017, 53 , 2590−2593.
  22. Lin, H.+; Tan, G. J.+; Shen, J. N.; Hao, S. Q.; Wu, L. M.;* Calta, N.; Malliakas, C.; Wang, S.; Uher, C.; Wolverton, C.; Kanatzidis, M. G.* Concerted Rattling in CsAg5Te3 Leading to Ultralow Thermal Conductivity and High Thermoelectric Performance. Angew. Chem. Int. Ed. 2016, 55 , 11431–11436.
  23. Shi, Y. F.; Chen, Y. K.; Chen, M. C.; Wu, L. M.;* Lin, H.; Zhou, L. J.; Chen, L.* Strongest Second Harmonic Generation in the Polar R3MTQ7 Family: Atomic Distribution Induced Nonlinear Optical Cooperation. Chem. Mater. 2015, 27 , 1876−1884.
  24. Yu, P.; Wu, L. M.;* Zhou, L. J.; Chen, L.* Deep-ultraviolet Nonlinear Optical Crystals: Ba3P3O10X (X = Cl, Br). J. Am. Chem. Soc. 2014, 136 , 480-487.
  25. Shen, J. N.; Wu, L. M.;* Zhang, Y. F. First-principles Studies of the TE Properties of [110]-Ge/Si Core/shell Nanowires with Different Surface Structures. J. Mater. Chem. A 2014, 2, 2538-2543.
  26. Zhou, L. J.; Zhang, Y. F.; Wu, L. M.* SiC2 Siligraphene and Nanotubes: Novel Donor Materials in Excitonic Solar Cells. Nano Lett. 2013, 13 , 5431-5436.
  27. Lin, H.; Chen, L.;* Zhou, L. J.; Wu, L. M.* Functionalization Based on the Substitutional Flexibility: Strong Middle IR Nonlinear Optical Selenides AXII4XIII5Se12. J. Am. Chem. Soc. 2013, 135 , 12914–12921.
  28. Lin, Z. S.; Chen, L.; Wang, L. M.; Zhao, J. T.; Wu, L. M.* A Promising Mid-temperature Thermoelectric Material Candidate: Pb/Sn-codoped In4PbxSnySe3. Adv. Mater. 2013, 25 , 4800–4806.
  29. Li, L. H.; Chen, L.;* Li, J. Q.; Wu, L. M.* Structural Characteistics, Electronic Structure, and Thermoelectric Property of New Sb-based Type-I clathrates From Density Functional Theory Calculations. Chem. Mater. 2010, 22 , 4007–4018.
  30. Wu, L. M.; Wu, X. T.; Chen, L.* Structural Overview and Structure-property Relationships of Iodoplumbate and Iodobismuthate. Coord. Chem. Rev. 2009, 253 , 2787–2804.
  31. Wu, L. M. ; Kim, S. H.; Seo, D. K.* Electron-precise/deficient La5-xCaxGe4 (3.4 ≤ x ≤ 3.8) and Ce5-xCaxGe4(3.0 ≤ x ≤ 3.3):  Probing Low-valence Electron Concentrations in Metal-rich Gd5Si4-type Germanides. J. Am. Chem. Soc. 2005, 127 , 15682-15683.
  32. Wu, L. M.; Seo, D. K.* Mn14Al56+xGe3-x(x = 0-0.6): A New Intermetallic Phase Containing Unprecedented "Half-broken" Mackay Icosahedra as Building Units. J. Am. Chem. Soc. 2004, 126 , 4398−4403.
  33. Chen, L.; Chen, Y. B.; Wu, L. M.* Synthesis of Uniform Cu2S Nanowires from Copper-thiolate Polymer Precursors by a Solventless Thermolytic Method. J. Am. Chem. Soc. 2004, 126 , 16334−16335.
  34. Wu, L. M.; Seo, D. K.* New Solid-gas Metathetical Synthesis of Binary Metal Polysulfides and Sulfides at Intermediate Temperatures: Utilization of Boron Sulfides. J. Am. Chem. Soc. 2004, 126 , 4676−4681

 

 


 
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